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Grafting of Molecularly Ordered Mesoporous Phenylene-Silica with Molybdenum Carbonyl Complexes: Efficient Heterogeneous Catalysts for the Epoxidation of Olefins

✍ Scribed by Ana C. Coelho; Salete S. Balula; Sofia M. Bruno; João C. Alonso; Nicolas Bion; Paula Ferreira; Martyn Pillinger; Anabela A. Valente; João Rocha; Isabel S. Gonçalves

Publisher: John Wiley and Sons
Year: 2010
Tongue: English
Weight: 445 KB
Volume: 352
Category: Article
ISSN: 1615-4150
DOI: 10.1002/adsc.201000042

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Highly efficient and excellent reusable catalysts of molybdenum(VI) complexes grafted on ZPS-PVPA for epoxidation of olefins with tert-BuOOH

✍ Zhongkai Hu; Xiangkai Fu; Yuedong Li; Xiaobo Tu 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 202 KB

## Abstract Four new kinds of heterogeneous catalysts for olefins epoxidation were obtained by grafting diamines on organic polymer–inorganic hybrid material, zirconium poly (styrene‐phenylvinylphosphonate)‐phosphate (ZPS‐PVPA), and subsequently coordinating with Schiff base Mo(VI) complexes. The c