Graft polymers with macromonomers. II. Copolymerization kinetics of methacrylate-terminated polystyrene and predicted graft copolymer structures
β Scribed by Schulz, G. O. ;Milkovich, R.
- Publisher
- John Wiley and Sons
- Year
- 1984
- Weight
- 986 KB
- Volume
- 22
- Category
- Article
- ISSN
- 0360-6376
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In order to calculate some kinetic parameters, such as the reactivity ratios, of the system β£-methylstyrene-methyl methacrylate, the bulk copolymerization of these two monomers with azobis isobutironitrile (AIBN) as a radical initiator was studied. Experiments were performed at the various temperatu
Polymerization of synthetic monomers is known to be influenced by the solvent, initiator system, dilution, temperature, etc. Substrates like starch granules, when used for graft copolymerization, can be expected to provide a drastically different environment for the monomers (as compared to the bulk