Graft polymerization of epoxide and alternating graft copolymerization of epoxide–acid anhydride onto a polystyrene backbone having an aminimide moiety
✍ Scribed by Sang-Do Lee; Fumio Sanda; Takeshi Endo
- Book ID
- 101271607
- Publisher
- John Wiley and Sons
- Year
- 1999
- Tongue
- English
- Weight
- 199 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0887-624X
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✦ Synopsis
Graft polymerization of glycidyl phenyl ether (GPE) and alternating graft copolymerization of GPE-succinic anhydride (SA) onto a polymer-supported aminimide were examined. The polymer-supported aminimide was synthesized by radical polymerization of 1,1-dimethyl-1-(2-hydroxy-3-(4-vinylbenzyloxy)propyl)amine 2-benzoylimide, which was prepared by the reaction of methyl benzoate with equimolar amounts of 1,1-dimethyl hydrazine and 4-glycidylmethylstyrene. This aminimide could initiate the polymerization of GPE and alternating copolymerization of GPE with SA to give the corresponding graft copolymers.