Graft copolymers from azodicarboxylate-functional pre-polymers: 1. Synthesis of azodicarboxylate-functional polystyrene
β Scribed by D.S. Campbell; D.E. Loeber; A.J. Tinker
- Publisher
- Elsevier Science
- Year
- 1984
- Tongue
- English
- Weight
- 543 KB
- Volume
- 25
- Category
- Article
- ISSN
- 0032-3861
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## Abstract For Abstract see ChemInform Abstract in Full Text.
Atom transfer radical polymerization (ATRP) was performed to prepare azide end-functional polystyrene (PSt-N 3 ) with predesigned molecular weight and narrow polydispersity. Then C 60 end-capped polystyrene was synthesized by reacting C 60 with PSt-N 3 . The UV-VIS, DSC, GPC characterizations indica
a-End-functionalized polymers and macromonomers of b-pinene were synthesized by living cationic isomerization polymerization in CH 2 Cl 2 at 040ΠC initiated with the HCl adducts [1; CH 3 CH(OCH 2 CH 2 X)Cl; X Γ chloride (1a), acetate (1b), and methacrylate ( 1c)] of vinyl ethers carrying pendant sub