Graft Copolymers by a Combination of ATRP and Two Different Consecutive Click Reactions
✍ Scribed by Tsarevsky, Nicolay V.; Bencherif, Sidi A.; Matyjaszewski, Krzysztof
- Book ID
- 120239614
- Publisher
- American Chemical Society
- Year
- 2007
- Tongue
- English
- Weight
- 106 KB
- Volume
- 40
- Category
- Article
- ISSN
- 0024-9297
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📜 SIMILAR VOLUMES
## Abstract Block copolymer synthesis via a combination of ATRP and RAFT using click chemistry is reported for the first time. A RAFT agent with a terminal propargyl group (PTTC) was synthesized and was used to polymerize butyl acrylate and gave quantitative monomer conversion. Azide‐terminated p(_
## Abstract ATRP using poly(propylene oxide) monofunctional macroinitiator was carried out with solketal methacrylate (SMA) and the non‐reactive PPO having two N~3~ terminal groups was removed by dissolution in an excess of __n__‐hexane. The resulting azido terminated AB diblock copolymer was ‘clic
## Abstract Three‐arm star block copolymers were successfully synthesized by combination of “core‐first” and “coupling‐onto” strategies. First, polystyrene 3‐arm star polymers (PS‐Br)~3~ with high bromine chain‐end functionality were synthesized by atom transfer radical polymerization (ATRP) using