A kinetic study of the graft copolymerization of methyl methacrylate onto jute fiber using KMn04-malonic acid redox initiator system has been made. Effects of the concentrations of malonic acid, monomer, and K M n 4 on graft yield have been studied. Besides, the effects of temperature, acid, and rea
Graft copolymerization reaction of water-emulsified methyl methacrylate with preirradiated jute fiber
โ Scribed by Ferdous Khan; S.R. Ahmad
- Publisher
- John Wiley and Sons
- Year
- 1997
- Tongue
- English
- Weight
- 186 KB
- Volume
- 65
- Category
- Article
- ISSN
- 0021-8995
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โฆ Synopsis
The graft copolymerization of methyl methacrylate with water-emulsified solution onto preirradiated jute fiber was studied. The jute samples were irradiated in the presence of air using a 60 Co source of gamma-radiation. A nonionic surfactant, commercially known as ''Scintron (Triton X-114),'' was used as an emulsifier. Homopolymerization was reduced by using 2-methyl-2-propene-1-sulfonic acid, sodium salt. The graft copolymerization was found to be dependent on the emulsifier concentration, radiation dose, temperature, monomer concentration, and reaction time. Maximum grafting level was achieved at temperatures in the range of 70-80ะC, and the optimal reaction time for maximum grafting level was found to be between 3 and 5 h, depending on the radiation doses.
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The kinetics of graft copolymerization of methyl methacrylate (MMA) onto chemically modified jute fibers initiated by the Ce(IV) -DMSO redox system was studied in the temperature range of 40-60ะC. By studying the effects of the concentration of the monomer, Ce(IV), and DMSO on the rate of grafting,
The role of persulfate-induced graft copolymerization of mixtures of acrylamide and methyl methacrylate at 50ะC in modifying mechanical properties of jute fibers of different compositions was studied in a limited aqueous system following a pretreatment technique. Results obtained indicate that such
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