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Graft copolymerization of styrene onto poly(vinyl p-nitrobenzoate) by chain transfer reaction

✍ Scribed by Shigeo Nakamura; Hideaki Sato; Kei Matsuzaki


Publisher
John Wiley and Sons
Year
1977
Tongue
English
Weight
31 KB
Volume
21
Category
Article
ISSN
0021-8995

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The effect of steric hindrance on the attack of growing polymer radicals to the reaction sites on a trunk polymer was examined in the graft copolymerization of styrene onto a trunk polymer with pendant aromatic nitro groups by chain transfer reaction of growing polymer radicals to the pendant nitro

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## Abstract The effect of addition of lignin model compounds on the polymerization rate and molecular weight of polymer in the radiation‐induced polymerization of styrene was studied. Guaiacol, a model for softwood lignin, reacted slowly with styrene radicals, while 2,6‐dimethoxyphenol, a hardwood