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Gold(III) complexes with 1,2-disulfanyl-1,2-dicarba-closo-dodecaborane. Synthesis and partial degradation reactions of [Au(S2C2B10H10 )2]− salts

✍ Scribed by Crespo, Olga; Gimeno, M. Concepción; Jones, Peter G.; Laguna, Antonio


Book ID
119943031
Publisher
The Royal Society of Chemistry
Year
1997
Tongue
English
Weight
365 KB
Volume
6
Category
Article
ISSN
1472-7773

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Cage opening of 1,2-(CH2OH)2-closo-1,2-C
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## Abstract The reaction of 1,2‐(CH~2~OH)~2~‐__closo__‐1,2‐C~2~B~10~ H~10~ carborane with 2‐(aminomethyl)‐pyridine in methylene chloride at room temperature led to the partial cage degradation of the __closo__ carborane and its conversion to the __nido__ derivative. The addition of cobalt chloride