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Gold(III) complexes containing 2-[(phenylazo)phenyl] as a chelating ligand

✍ Scribed by J. Vicente; M.T. Chicote; M.D. Bermudez; M. Garcia-Garcia

Publisher: Elsevier Science
Year: 1985
Tongue: English
Weight: 370 KB
Volume: 295
Category: Article
ISSN: 0022-328X
DOI: 10.1016/0022-328x(85)88079-7

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## Abstract Heating [Rh(dtbpy)(κ~2~‐__C,C′__‐CH~2~CMe~2~C~6~H~4~)(CH~2~CMe~2~Ph)] (1; dtbpy = 4,4′‐di‐__tert__‐butyl‐2,2′‐bipyridyl) in __p__‐xylene at 110 °C resulted in the formation of the 2‐__tert__‐butylphenyl complex [Rh(dtbpy)(κ~2~‐__C,C′__‐CH~2~CMe~2~C~6~H~4~)(C~6~H~4~__t__Bu‐2)] (3). Treat