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Gold(I)-selenolate complexes: Synthesis, characterization and ligand exchange reactions

✍ Scribed by KRISHNA P BHABAK, GOVINDASAMY MUGESH

Book ID
113094116
Publisher
Indian Academy of Sciences,Royal Society of Chemistry
Year
2011
Tongue
English
Weight
336 KB
Volume
123
Category
Article
ISSN
0253-4134

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## Abstract The reactions of the tetraphosphane donor ligand (Ph~2~PCH~2~)~2~NCH~2~CH~2~N(CH~2~PPh~2~)~2~ with the gold precursors [AuCl(tht)] or [Au(C~6~F~5~)(tht)] (tht = tetrahydrothiophene) leads to complexes [Au~4~R~4~{(Ph~2~PCH~2~)~2~NCH~2~CH~2~N(CH~2~PPh~2~)~2~}] [R = Cl (1) or C~6~F~5~ (2)]