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Gold(I) Phosphido Complexes: Synthesis, Structure, and Reactivity

✍ Scribed by Stefanescu, Diana M.; Yuen, Holming F.; Glueck, David S.; Golen, James A.; Zakharov, Lev N.; Incarvito, Christopher D.; Rheingold, Arnold L.

Book ID: 126028755
Publisher: American Chemical Society
Year: 2003
Tongue: English
Weight: 236 KB
Volume: 42
Category: Article
ISSN: 0020-1669
DOI: 10.1021/ic035006e

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The coordination behaviour of 2,6-disilyl-substituted characterized. The formation of 6 results from a [4 + 2] cycloaddition between one alkynyl group of each phosphinine phosphinines towards gold(I) has been examined. The reaction of the bis(trimethylsilyl)phosphinine 1 with [AuCl(SMe 2 )] gives wi