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Gold(I) complexes of azoles

✍ Scribed by Zoran D. Matović; Dušan J. Radanović; G. Ponticelli; P. Scano; I. A. Efimenko

Publisher
Springer
Year
1994
Tongue
English
Weight
362 KB
Volume
19
Category
Article
ISSN
0340-4285

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✦ Synopsis

Dimethyl sulphide)AuCl reacts with azoles to give adducts [-LAnX]z [-L = N-methylimidazole (N-MeIm), N-ethylimidazole (N-EtIm), N-propylimidazole (N-Prim), 2methylbenzoxazole (2-MeBO) and 2,5-dimethylbenzoxazole (2,5-diMeBO); X = C1 or Br] which were characterized analytically and spectroscopically, including 1H-n.m.r.I.r. and Raman studies showed that the compounds were binuclear with bridging halogen atoms. A nitrogen-containing ligand was coordinated to nitrogen N(3) atom of the azole ring in monodentate fashion.

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