Gold(I)-Catalyzed Tandem Rearrangement–Nucleophilic Substitution of α-Acetoxy Alkynyl Oxiranes or Aziridines: Efficient Approach to Furans and Pyrroles

✍ Scribed by Aurélien Blanc; Aurélien Alix; Jean-Marc Weibel; Patrick Pale

• Publisher: John Wiley and Sons
• Year: 2010
• Tongue: English
• Weight: 215 KB
• Volume: 2010
• Category: Article
• ISSN: 1434-193X
• DOI: 10.1002/ejoc.200901331

✦ Synopsis

Abstract

Highly substituted furans and pyrroles were efficiently formed by a new gold(I)‐catalyzed tandem rearrangement–nucleophilic substitution of acetoxylated alkynyl oxiranes and aziridines in the presence of various nucleophiles.