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Gold(I)-Catalyzed Synthesis of γ-Hydroxyketones from 5-Allyloxy-1-ynes

✍ Scribed by Cheong, Jae Youp; Im, Donghong; Lee, Miryeong; Lim, Wontaeck; Rhee, Young Ho

Book ID
127050303
Publisher
American Chemical Society
Year
2011
Tongue
English
Weight
793 KB
Volume
76
Category
Article
ISSN
0022-3263

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ChemInform Abstract: Gold(I)-Catalyzed S
ChemInform Abstract: Gold(I)-Catalyzed Synthesis of γ-Hydroxyketones from 5-Allyloxy-1-ynes.
✍ Jae Youp Cheong; Donghong Im; Miryeong Lee; Wontaeck Lim; Young Ho Rhee 📂 Article 📅 2011 🏛 John Wiley and Sons ⚖ 47 KB

## Abstract It is found that treatment of 5‐allyloxy‐1‐ynes with catalytic amounts of Au(I) complex in aqueous solution results in unexpected formation of γ‐hydroxyketones like (II), (IV), and (VI).