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Gold(I)-Catalyzed Rearrangement of N -Aryl 2-Alkynylazetidines to Pyrrolo[1,2- a ]indoles

✍ Scribed by Kern, Nicolas; Hoffmann, Marie; Blanc, Aurélien; Weibel, Jean-Marc; Pale, Patrick


Book ID
118733809
Publisher
American Chemical Society
Year
2013
Tongue
English
Weight
490 KB
Volume
15
Category
Article
ISSN
1523-7060

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Rearrangement of spiro[2H-1-benzopyran-2
✍ Vytas Martynaitis; Algirdas Šačkus; Ulf Berg 📂 Article 📅 2002 🏛 Journal of Heterocyclic Chemistry 🌐 English ⚖ 68 KB

## Abstract Heating of 1′‐(__N__‐substituted carbamoyl)methylspiro[2__H__‐1‐benzopyran‐2,2′‐[2__H__]indoles] with potassium hydroxide in ethanol yields diastereomeric 5a,13‐methano‐6__H__‐1,3‐benzoxazepino[3,2‐__a__]indole‐12‐carbox‐amides. Reduction of the latter with sodium borohydride affords 1,