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Gold(I)-Catalyzed Formation of Benzo[b]furans from 3-Silyloxy-1,5-enynes

✍ Scribed by Prof. Dr. A. Stephen K. Hashmi; M. Sc. Weibo Yang; Dr. Frank Rominger

Publisher: John Wiley and Sons
Year: 2011
Tongue: English
Weight: 291 KB
Volume: 50
Category: Article
ISSN: 0044-8249
DOI: 10.1002/anie.201100989

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## Abstract A highly efficient method has been developed for the one‐pot synthesis of multi‐ring heterocyclic compounds such as pyrrolo‐/pyrido[2,1‐__b__]benzo[__d__][1,3]oxazin‐1‐ones from __o__‐aminobenzyl alcohols __via__ a gold(I)‐catalyzed tandem coupling/cyclization reaction. Significantly, t