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Gold(I)-Catalyzed Alkoxyhalogenation of β-Hydroxy-α,α-Difluoroynones

✍ Scribed by Marie Schuler; Franck Silva; Carla Bobbio; Arnaud Tessier; Véronique Gouverneur

Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
342 KB
Volume
120
Category
Article
ISSN
0044-8249

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The formation of 4-alkoxy-2(5H)-furan-A C H T U N G T R E N N U N G ones was achieved via tandem alkoxylation/lactonization of g-hydroxy-a,b-acetylenic esters catalyzed by 2 mol% of [2,6-bis(diisopropylphenyl)imidazol-2-ylidine]gold bis(trifluoromethanesulfonyl)imidate