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Gold nanoparticles promote the catalytic activity of ceria for the transalkylation of propylene carbonate to dimethyl carbonate

✍ Scribed by Juárez, Raquel; Corma, Avelino; García, Hermenegildo

Book ID
121687005
Publisher
Royal Society of Chemistry
Year
2009
Tongue
English
Weight
135 KB
Volume
11
Category
Article
ISSN
1463-9262

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Activity of ceria and ceria-supported go
Activity of ceria and ceria-supported gold nanoparticles for the carbamoylation of aliphatic amines by dimethyl carbonate
✍ Juárez, Raquel; Corma, Avelino; García, Hermenegildo 📂 Article 📅 2011 🏛 International Union of Pure and Applied Chemistry 🌐 English ⚖ 254 KB

Aliphatic amines react sluggishly with dimethyl carbonate (DMC) to give a mixture of N-methylation and carbamoylation. Nanoparticulated ceria as catalyst increases, in general, conversion and selectivity toward carbamoylation. This increase in catalytic activity and selectivity toward carbamoylation