Gold Nanoparticles Electrodeposited on Ordered Mesoporous Carbon as an Enhanced Material for Nonenzymatic Hydrogen Peroxide Sensor
✍ Scribed by Lixia Wang; Xiangjie Bo; Jing Bai; Liande Zhu; Liping Guo
- Publisher
- John Wiley and Sons
- Year
- 2010
- Tongue
- English
- Weight
- 344 KB
- Volume
- 22
- Category
- Article
- ISSN
- 1040-0397
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✦ Synopsis
Abstract
A facile and controllable electrodeposition method was developed to directly attach gold nanoparticles (GNPs) on ordered mesoporous carbon (OMC). The GNPs on OMC substrate were characterized by scanning electron microscopy (SEM), X‐ray diffraction (XRD) and X‐ray photoelectron spectrometer (XPS), respectively. A nonenzymatic hydrogen peroxide (H~2~O~2~) sensor was fabricated on GNPs‐OMC/GCE. The sensor demonstrated a fast amperometric response (2.5 s), a wide linear range toward H~2~O~2~ concentrations between 2.0×10^−6^ and 3.92×10^−3^ M (R=0.999), and a low detection limit of 0.49 µM (S/N=3). Moreover, it exhibited good reproducibility and long‐term stability. The excellent electrocatalytical activity might be attributed to the synergistic effect of OMC and GNPs.