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Gold-Catalyzed Intermolecular Addition of Carbonyl Compounds to 1,6-Enynes

✍ Scribed by Mathias Schelwies; Adrian L. Dempwolff; Frank Rominger; Günter Helmchen

Publisher: John Wiley and Sons
Year: 2007
Tongue: English
Weight: 125 KB
Volume: 46
Category: Article
ISSN: 0044-8249
DOI: 10.1002/anie.200701378

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The authors have recently found that the configuration of diene 64 (Ar = p-MeOC 6 H 4 ) in Scheme 6 was incorrectly assigned. The major isomer has a cis configuration, whereas the configuration of related compounds 62 and 66 (Ar = Ph and p-O 2 NC 6 H 4 ) is trans as reported. The correct configurati