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Gold-Catalyzed Hydroarylation of Alkynes

✍ Scribed by Manfred T. Reetz; Knut Sommer

Publisher
John Wiley and Sons
Year
2003
Tongue
English
Weight
228 KB
Volume
2003
Category
Article
ISSN
1434-193X

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Gold-Catalyzed Hydroarylation of Alkynes
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## Abstract The cyclization of differently substituted aryl alkynes with Pt^II^ or Au^I^ catalysts proceeds by __endo‐dig__ pathways. When Ag^I^ was used to generate reactive cationic Au^I^ catalysts, 2__H__‐chromenes dimerize to form cyclobutane derivatives by a Ag^I^‐catalyzed process. A DFT stud