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Gold-Catalyzed Heterogeneous Aerobic Dehydrogenative Amination of α,β-Unsaturated Aldehydes to Enaminals

✍ Scribed by Jin, Xiongjie; Yamaguchi, Kazuya; Mizuno, Noritaka


Book ID
121805370
Publisher
John Wiley and Sons
Year
2013
Tongue
English
Weight
765 KB
Volume
53
Category
Article
ISSN
0044-8249

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## Abstract The direct organocatalytic enantioselective epoxidation of α,β‐unsaturated aldehydes with different peroxides is presented. Proline, chiral pyrrolidine derivatives, and amino acid‐derived imidazolidinones catalyze the asymmetric epoxidation of α,β‐unsaturated aldehydes. In particular, p