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Gold- and Platinum-Catalyzed Cycloisomerization of Enynyl Esters versus Allenenyl Esters: An Experimental and Theoretical Study

✍ Scribed by Nicolas Marion; Gilles Lemière; Andrea Correa; Chiara Costabile; Rubén S. Ramón; Xavier Moreau; Pierre de Frémont; Rim Dahmane; Alexandra Hours; Denis Lesage; Jean-Claude Tabet; Jean-Philippe Goddard; Vincent Gandon; Luigi Cavallo; Louis Fensterbank; Max Malacria; Steven P. Nolan


Book ID
102796096
Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
536 KB
Volume
15
Category
Article
ISSN
0947-6539

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✍ Abhilash N. Pillai; Cherumuttathu H. Suresh; Vijay Nair 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 825 KB

## Abstract A systematic study of the addition of various 1,2‐acyclic diones to activated acetylenic esters catalyzed by pyridine under mild conditions is described. This reaction provides a new protocol for the stereoselective synthesis of 1,2‐diaroyl maleates. The exclusive formation of the __cis