Glyoxalate-Derived Aldimines in Cycloaddition Reactions with Olefins
✍ Scribed by Francisco Palacios; Concepción Alonso; María Fuertes; Jose M. Ezpeleta; Gloria Rubiales
- Publisher
- John Wiley and Sons
- Year
- 2011
- Tongue
- English
- Weight
- 656 KB
- Volume
- 2011
- Category
- Article
- ISSN
- 1434-193X
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📜 SIMILAR VOLUMES
## 3-Diazo-4-methyl-5-phenylpyrazole readily adds to electron rich olefins to give 1,7-cycloadducts, The mechanism of the reaction consists of an initial 1,3-dipolar cycloaddition followed by a subsequent rearrangement.
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.
## Abstract magnified image We report here on some 3+2 dipolar cycloaddition reactions of propargyl, allyl and cyano substituted 2,3‐benzodiazepines with __in situ__ generated nitrile oxides and diazomethane. The reactivity of carbon‐nitrogen double bonds of the 5__H__‐[2,3]benzodiazepine ring sys