Glycosylidene Carbenes. Part 20. Synthesis of deprotected, spiro-linked C-glycosides of C60

✍ Scribed by Peter Uhlmann; Eva Harth; Andrew B. Naughton; Andrea Vasella

• Publisher: John Wiley and Sons
• Year: 1994
• Tongue: German
• Weight: 481 KB
• Volume: 77
• Category: Article
• ISSN: 0018-019X
• DOI: 10.1002/hlca.19940770820

✦ Synopsis

A variety of ambiphilic derivatives of CG0 have been prepared [2-151, and their biological [7] [15-18] and physical properties, in particular their ability to form self-assemblingmonolayers [3] [9] [I31 (19-241, have been investigated. HELV~TICA CHIMICA ACTA ~ Vol. 77 (1 994) Scheme ~?&+"// m T -o O B % / RO N N 1 2 R=Bn 7 3 R = ? N 4 R' = H, R2 = BnQ R3 = R' = R3 = Bn 5 R' = H. R2 = PivO. R3 = R' = R' = Piv 6 R' = BnO, R2 = H