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GLC studies of diffusion of some selected solvents in polypropylene and the calculation of the activation energy of diffusion

✍ Scribed by Abushihada, A. M. ;Shunbo, F. E. ;Al-Sultan, Y. Y.


Publisher
John Wiley and Sons
Year
1978
Tongue
English
Weight
265 KB
Volume
1
Category
Article
ISSN
0935-6304

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✦ Synopsis


Abstract

A thorough survey of the past and current available literature shows that the diffusion of the solvents toluene, ethylbenzene, ortho‐, meta‐, and para‐xylenes in polypropylene has not been studied so far, although such studies find practical applications in various industrial problems. Diffusitives and the activation energies of the above mentioned solvents in polypropylene were determined in the temperature range of 45–120Β°C by gas chromatography. The values obtained in this communication compare fairly with those determined by conventional techniques for analogous systems, confirming the reliability of the gas chromatography as a powerful tool for diffusion measurement and the authenticity of the data presented herein.


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Poly(methacrylonitrile) (PMAN) samples in the shape of a cylinder used in this study were obtained from methacrylonitrile by bulk polymerization. The electron spin resonance (ESR) method has been used to calculate oxygen diffusion coefficient (D) into PMAN samples exposed to high-energy radiation at