Poly(ethyl a-benzoyloxymethylacrylate) (EBMA) and copolymers of methyl methacrylate (MMA) with EBMA have been prepared by free radical polymerization. Monomer precursors of ethyl a-benzoyloxymethylacrylate have likewise been polymerized. Glass transition temperatures (T g ) of homo and copolymers ha
Glass transition temperatures of butyl acrylate–methyl methacrylate copolymers
✍ Scribed by M. Fernández–García; R. Cuervo–Rodriguez; E. L. Madruga
- Publisher
- John Wiley and Sons
- Year
- 1999
- Tongue
- English
- Weight
- 171 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0887-6266
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✦ Synopsis
The glass transition temperatures T g of butyl acrylate-methyl methacrylate copolymers obtained by free radical polymerization in 3 and 5 mol/L benzene solution have been measured using differential scanning calorimetry (DSC) and the values have been correlated using Johnston's equation with inter-intramolecular copolymer structure. From the data calculated with copolymer prepared at low conversion, the variation of glass transition temperature with copolymer conversion has been theoretically predicted.
📜 SIMILAR VOLUMES
## Abstract Poly(methyl methacrylate‐__ran__‐styrene) copolymers were synthesized under monomer‐starved conditions by emulsion copolymerization. The glass‐transition temperatures (__T__~__g__~'s) of the copolymers were measured by differential scanning calorimetry (DSC) and torsional braid analysis