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Glass transition temperatures of butyl acrylate–methyl methacrylate copolymers

✍ Scribed by M. Fernández–García; R. Cuervo–Rodriguez; E. L. Madruga


Publisher
John Wiley and Sons
Year
1999
Tongue
English
Weight
171 KB
Volume
37
Category
Article
ISSN
0887-6266

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✦ Synopsis


The glass transition temperatures T g of butyl acrylate-methyl methacrylate copolymers obtained by free radical polymerization in 3 and 5 mol/L benzene solution have been measured using differential scanning calorimetry (DSC) and the values have been correlated using Johnston's equation with inter-intramolecular copolymer structure. From the data calculated with copolymer prepared at low conversion, the variation of glass transition temperature with copolymer conversion has been theoretically predicted.


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