Since the synthesis of bulk glassy alloys in multi-component Ln- [1] (Ln: lanthanide metal) and Mg- [2] based alloys by the copper mold casting method in 1989, much effort has been devoted to develop new bulk glassy alloys exhibiting high glass-forming ability (GFA) and useful engineering properties
Glass-forming ability and mechanical properties of Cu50Zr50−xTix alloys
✍ Scribed by H. Men; S.J. Pang; T. Zhang
- Publisher
- Elsevier Science
- Year
- 2005
- Tongue
- English
- Weight
- 320 KB
- Volume
- 408
- Category
- Article
- ISSN
- 0921-5093
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✦ Synopsis
Glass-forming ability (GFA) of Cu 50 Zr 50-x Ti x (x = 0-50 at.%) alloys was investigated by melt-spinning and copper mould casting methods. Bulk metallic glasses can be formed in the composition range of 0-15 and 35-45 at.% Ti. The x = 7.5 and 40 alloys show the best GFA in the local compositional vicinity, and critical diameters for glass formation is 5 and 3 mm, respectively. The GFA of the x = 20-30 alloys was degraded due to appearance of a Mg 2 Zn-type Laves phase in the center portion of Cu-Zr-Ti diagram. The supercooled liquid temperature region and reduced glass transition temperature are 40 K, 0.
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This paper presents an influence of Ag addition on the glass-forming ability and devitrification behavior of Cu-Zr glassy alloys on heating. The crystallization kinetics and structure changes in Cu 45 Zr 45 Ag 10 and Cu 35 Zr 45 Ag 20 glassy alloys on heating were studied by X-ray diffraction, trans