Gibbs free energies of transfer of cryptand (2,2,2) and silver (2,2,2) perchlorate from water to acetonitrile-water mixtures
β Scribed by Cox, B. G.; Guminski, C.; Schneider, H.
- Book ID
- 121451162
- Publisher
- American Chemical Society
- Year
- 1982
- Tongue
- English
- Weight
- 513 KB
- Volume
- 104
- Category
- Article
- ISSN
- 0002-7863
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π SIMILAR VOLUMES
A complexation scheme involving a conformational equilibrium of the ligand is proposed to explain the difference in free energies of transfer between metal complex and ligand from water to non-aqueous solvents. In a recent paper Abraham and Ling' have reported the thermodynamic parameters of transf
Solubility data are reported at 298.15K for LiF, NaF and, to a lesser extent, KF in aqueous mixtures of dimethylsulphoxide (DMSO), propanone, (acetone, AC) and 2-methylpropan-2-01 (tertiary butanol, &BuOH) over virtually the entire solvent composition range. These data have been combined wherever po