The Second Law of Thermodynamics is investigated with respect to its value as an indicator of the direction of the evolutionary process. Non-thermodynamic entropy concepts and possible errors in the use of thermodynamic entropy are discussed. The importance of genuine thermodynamic potentials and th
Gibbs entropy and irreversibility
✍ Scribed by A. Pérez-Madrid
- Publisher
- Elsevier Science
- Year
- 2004
- Tongue
- English
- Weight
- 202 KB
- Volume
- 339
- Category
- Article
- ISSN
- 0378-4371
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✦ Synopsis
This contribution is dedicated to elucidating the role of the Gibbs entropy in the discussion of the emergence of irreversibility in the macroscopic world from the microscopic level. By using an extension of the Onsager theory to the phase space we obtain a generalization of the Liouville equation describing the evolution of the distribution vector in the form of a master equation. This formalism leads in a natural way to the breaking of the BBGKY hierarchy. As a particular case we derive the Boltzmann equation.
📜 SIMILAR VOLUMES
The Gibbs and Boltzm~nn description of a system are contrasted for the entropy of a general Markov process. An H theorem is established for the Gibbs entropy. The master equation for non-stationary processes is introduced to initiate a discussion of the p.henomenological equations in the two descrip