Germane decomposition: Kinetic and thermochemical data
โ Scribed by V. N. Smirnov
- Book ID
- 110170883
- Publisher
- Springer
- Year
- 2007
- Tongue
- English
- Weight
- 164 KB
- Volume
- 48
- Category
- Article
- ISSN
- 0023-1584
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
## Abstract A microcanonical analysis of the extended kinetic method is performed using statistical rate calculations based on orbiting transition state theory. The model systems simulate polydentate bases M which exhibit losses of entropy upon protonation of up to 35 kJ mol^โ1^ K^โ1^. It is shown
The homogeneous gas-phase thermal decomposition kinetics of germane have been measured in a single-pulse shock tube between 950 and 1060 K at pressures around 4000 torr. The initial decomposition is GeH4 -GeH2 + H2 in its pressure-dependent regime, with log k ~~~~( 4 m ) = 13.83 f 0.78 -50,750 f 357