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Geometry dependence of intramolecular photoinduced electron transfer in synthetic zinc-ferric hybrid diporphyrins

✍ Scribed by Osuka, Atsuhiro; Maruyama, Kazuhiro; Mataga, Noboru; Asahi, Tsuyoshi; Yamazaki, Iwao; Tamai, Naoto


Book ID
121245699
Publisher
American Chemical Society
Year
1990
Tongue
English
Weight
272 KB
Volume
112
Category
Article
ISSN
0002-7863

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Excited-state dynamics of a series of conformationally restricted magnesium-free-base hybrid diporphyrins (MgP-HsP) have been studied by fluorescence lifetime measurement and picosecond time-resolved transient absorption spectroscopy. Upon photoexcitation in toluene and THF, intramolecular singlet-s

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Intramolecular photoinduced electron transfer reaction of a series of fixed distance triads consisting of free-base porphyrin, zinc porphyrin, and quinone or pyromellitimide have been investigated by means of steady-state fluorescence spectroscopy, picosecond time-resolved fluorescence spectroscopy,