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Geometry and solvolysis of exo-anti-tricyclo[3.1.1.02,4]heptan-6-yl-p-nitrobenzoate

โœ Scribed by Masamune, S.; Vukov, R.; Bennett, M. J.; Purdham, J. T.


Book ID
125942100
Publisher
American Chemical Society
Year
1972
Tongue
English
Weight
393 KB
Volume
94
Category
Article
ISSN
0002-7863

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Solvolysis and direct observation studie
โœ A.F. Diaz; D.L. Harris; M. Sakai; S. Winstein ๐Ÿ“‚ Article ๐Ÿ“… 1971 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 206 KB

Recent studies on the anionic reactions of bicyclooctadiene, II, strongly suggest the direct involvement of the 6,7-olefinic group with the allylic anion to form the intermediate bis-homocyclopentadienyl anion, III, in accord with the bonding interaction predicted by HMO calculations.