Geometry and nature of the binding of the pre-reactive complex C2H4…ClF from its rotational spectrum

Nature and angular geometry of the pre-r

Nature and angular geometry of the pre-reactive complex thiirane-chlorine monofluoride from its rotational spectrum

✍ C.M. Evans; J.H. Holloway; A.C. Legon 📂 Article 📅 1996 🏛 Elsevier Science 🌐 English ⚖ 666 KB

The rotational spectrum of the pre-reactive complex thiirane-ClF was detected with a fast-mixing nozzle in an FF microwave spectrometer. Rotational constants, centrifugal distortion constants, Cl-nuclear quadrupole and spin-rotation coupling constants were determined for the isotopomers (CH2)2S '''

Characterisation of a pre-reactive inter

Characterisation of a pre-reactive intermediate in gas-phase mixtures of fluorine and ammonia: the rotational spectrum of the H3N…F2 complex

✍ H.I. Bloemink; K. Hinds; J.H. Holloway; A.C. Legon 📂 Article 📅 1995 🏛 Elsevier Science 🌐 English ⚖ 491 KB

A weakly bound complex of NH 3 and F 2 has been detected as a pre-reactive intermediate in mixtures of the component gases and characterised by means of its ground-state rotational spectrum. Chemical reaction of NH 3 and F 2 was precluded by using a fast-mixing nozzle in a Fourier-transform microwav

Are B…ClF bonds linear? The angular geo

Are B…ClF bonds linear? The angular geometry of a pre-reactive complex of oxirane and chlorine monofluoride from rotational spectroscopy

✍ H.I. Bloemink; C.M. Evans; J.H. Holloway; A.C. Legon 📂 Article 📅 1996 🏛 Elsevier Science 🌐 English ⚖ 768 KB

A pre-reactive complex formed by oxirane and CIF was characterised through the ground-state rotational spectra of the isotopomers (CH2)20.-. 35CIF and (CH2)20.-. 37C1F. The complex has C s symmetry, with the O.-. C1-F nuclei confined to the symmetry (ac) plane. Determination of the complete CI nucle

Syntheses and reactivity of p-substitute

Syntheses and reactivity of p-substituted benzonitrile complexes derived from dicyclopentadienyl-molybdenum and -tungsten. Oxidative electrochemistry. The crystal structure of [Mo(η5-C5H5)2(SC6H5)(p-(CH3)2NC6H4CN)][PF6]

✍ M.A.A.F. de C.T. Carrondo; A.R. Dias; M.Helena Garcia; Pedro M. Matias; M.Paula 📂 Article 📅 1990 🏛 Elsevier Science 🌐 English ⚖ 962 KB

Syntheses and reactivity of p-substitute

Syntheses and reactivity of p-substituted benzonitrile complexes derived from dicyclopentadienyl-molybdenum and -tungsten. Oxidative electrochemistry. The crystal structure of [Mo(ν5-C5H5)2(SC6H5)(p-(CH3)2NC6H4CN)][PF6: by M.A.A.F. de C.T. Carrondo, A.R. Dias, M. Helena Garcia, Pedro M. Matias, M. Paula Robalo, M.L.H. Green, J. Higgins and Y.Y. Yang (J. Organomet. Chem., 395 (1990) 279–292)

📂 Article 📅 1991 🏛 Elsevier Science 🌐 English ⚖ 46 KB