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Geometrics of the radical anions of ethylene, fluoroethylene, 1,1-difluoroethylene, and tetrafluoroethylene

โœ Scribed by Paddon-Row, Michael N.; Rondan, Nelson G.; Houk, K. N.; Jordan, K. D.


Book ID
124063987
Publisher
American Chemical Society
Year
1982
Tongue
English
Weight
413 KB
Volume
104
Category
Article
ISSN
0002-7863

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The structure of the 1-1-difluoroethylen
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A structure wit& a pyramidal -CFi group is shown to describe satisfactorily hyperfine interactions in CH&F? radical anions withiri the frahework of the INDO method. The factors responsible for the substantial difference in the degree of spin density delocalization on F in CHzCF? and Cz IQ are analyz