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Geometrically Induced Loss of Aromaticity in Bridged [14] Annulenes: syn-1,6-Ethano-8,13-methano[14]annulene

✍ Scribed by Prof. Dr. Emanuel Vogel; Dr. Hans M. Deger; Dipl.-Chem. Peter Hebel; Dr. Johann Lex

Publisher
John Wiley and Sons
Year
1980
Tongue
English
Weight
334 KB
Volume
19
Category
Article
ISSN
0044-8249

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**Detailed structural information is obtainable from ^3^__J__(H,H) values** in unsaturated ring systems. Accurate analysis of the 400‐MHz ^1^H‐NMR spectrum of the title compound revelated a temperature‐dependent equilibrium between the double bond isomers __(1)__β‡Œ__(2)__ (see previous communication)