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Geometrical limitations in the intramolecular addition of unsymmetrical allylsilanes to enones

✍ Scribed by George Majetich; Ken Hull; Jean Defauw; Thomas Shawe


Publisher
Elsevier Science
Year
1985
Tongue
French
Weight
257 KB
Volume
26
Category
Article
ISSN
0040-4039

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πŸ“œ SIMILAR VOLUMES


Chemoselectivity in the conjugate additi
✍ George Majetich; Ada M. Casares; D. Chapman; M. Behnke πŸ“‚ Article πŸ“… 1983 πŸ› Elsevier Science 🌐 French βš– 229 KB

The allylic carbanion species generated by treatment of allylsilane with fluoride ion undergoes highly chemoselective conjugate addition to a series of Michael acceptors for which alternative known allylation procedures proved less general. Conjugate addition of most nucleophilic reagents to an ~1