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Geometrical Isomerism in 4-Phosphorinanols

โœ Scribed by Shook, Howard E.; Quin, Louis D.

Book ID
126121132
Publisher
American Chemical Society
Year
1967
Tongue
English
Weight
860 KB
Volume
89
Category
Article
ISSN
0002-7863

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๐Ÿ“œ SIMILAR VOLUMES

Geometrical isomerism of 4-ethyl-1-methy
Geometrical isomerism of 4-ethyl-1-methyl-4-phosphorinanol
โœ Louis D. Quin; Howard E. Shook Jr. ๐Ÿ“‚ Article ๐Ÿ“… 1965 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 217 KB

The configurational stability of the trivalent phosphorus atom is sufficient to permit optically active derivatives to exist (1-J). It follows that suitably substituted cyclic compounds with trivalent phosphorus should exist in cis and trans -isomeric forms. Qoldwhite (4) has presented evidence fro

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โœ Sidney I. Featherman; Louis D. Quin ๐Ÿ“‚ Article ๐Ÿ“… 1973 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 205 KB

We have found that "C nmr spectroscopy is a powerful tool for the determination of the structures of &, trans isomers in the phosphorinane family. It is more definitive than 'H nmr spectroscopy; the carbon signals are well separated and have several unique features pointing to the structure, whereas