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Geometrical and electronic cooperativity in cation-mediated electrochemical reductions of anthraquinone-substituted podands

✍ Scribed by Deborah A Gustowski; Milagros Delgado; Vincent J Gatto; Luis Echegoyen; George W Gokel

Publisher: Elsevier Science
Year: 1986
Tongue: French
Weight: 212 KB
Volume: 27
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)84829-7

No coin nor oath required. For personal study only.

✦ Synopsis

Unlike their nitroaromatic counterparts, podands based upon the anthraquinone skeleton bind cations more strongly when reduced because of a combination of geometrical and electronic factors.

We wish to report the first example of an electrochemically switched anthraquinone podand, the success of which can be attributed to a combination of electronic and geometrical factors.

L.: Goli.

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