Geometric isomerism of copper(II) with monochlorobenzhydrazide chelate complexes

✍ Scribed by Oleg V. Mikhailov

• Book ID: 104637994
• Publisher: Springer
• Year: 1994
• Tongue: English
• Weight: 325 KB
• Volume: 19
• Category: Article
• ISSN: 0340-4285
• DOI: 10.1007/bf00139310

✦ Synopsis

Chelate complexes having a 1:2 Cu H ion:(singly deprotonated ligand ratio, formed from Cu" including 2-, 3-and 4-chlorobenzhydrazides, (C1C6H,C(O)NHNH2) have been studied in the pH > 10 region. With the 2-chloro substituted derivative the cis-isomer is formed, whereas with the 3-and 4-chloro substituted derivatives trans-isomers are formed. The complexing schemes are described.