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Geochemistry of thermal waters from Morocco

โœ Scribed by Rosa Cidu; Saadia Bahaj


Publisher
Elsevier Science
Year
2000
Tongue
English
Weight
453 KB
Volume
29
Category
Article
ISSN
0375-6505

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โœฆ Synopsis


Thermal waters from the Rif (Northern Morocco) have temperatures in the 31ยฑ528C range, near-neutral pH (6.3ยฑ7.0), variable redox conditions (from ร€0.2 to 0.5 V) and a wide range of total dissolved solids (<1ยฑ27 g/l). The D/H and 18 Oa 16 O isotopic ratios of the water suggest a meteoric origin for the thermal waters. The main chemical composition is sodium-chloride, resulting from the interaction of water with marine sediments. Highsalinity waters show high concentrations of B, Li, and Sr, while other minor components and metals (e.g., Fe, Mn, Zn, Cd, Pb, Cu, Co, Ni, As, Sb and Hg) are usually very low. At Oulmes (Massif Central) the water shows 428C, a pH of 5.9, TDS of 1.5 g/l, sodiumbicarbonate chemical composition, and high P-CO 2 . This water ยฏows out of granite rocks and is characterised by high concentrations of SiO 2 , Li, Rb, Cs, Fe, Mn, Be and As. Chemical equilibrium studies show that the thermal waters are close to equilibrium with respect to calcite, dolomite, chalcedony and kaolinite, while equilibrium with respect to gypsum and barite occurs in the sulphate-rich waters. Chemical geothermometers suggest deep temperatures close to 1008C for the warmest water in the Rif (My Yacoub: 528C at the emergence), and about 1308C at Oulmes.


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