Generation of Tris(dialkylamino)cyclopropenyl Radical Dications by Pulse Radiolysis and Redox Potential Determination for the C 3 (NEt 2 ) 3•2+ /C 3 (NEt 2 ) 3+ and C 3 (NC 5 H 10 ) 3•2+ /C 3 (NC 5 H 10 ) 3+ Couples
✍ Scribed by Surman, Peter W. J.; Anderson, Robert F.; Packer, John E.; Taylor, Michael J.
- Book ID
- 126302462
- Publisher
- American Chemical Society
- Year
- 1997
- Tongue
- English
- Weight
- 105 KB
- Volume
- 101
- Category
- Article
- ISSN
- 1089-5639
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📜 SIMILAR VOLUMES
Formation of methyl radicals via the consecutive reactions H+C2H,+M+C2H,+M ( I ) and H+CLH,+CH,+CH3 (?a) was initiated by pulse radiolysis of IO-100 mbar Hz in the presence of ethylene. The kinetics of CH, were studied by monitoring the transient infrared absorption at the Q( 3, 3) line of the u,=O+
Trimethylamine-bis(trifluoromethyl) boranes R(CF 3 ) 2 B ´NMe 3 (R = cis/trans-CF 3 CF=CF (1/2), HCºC (3), H 2 C=CH (4), C 2 H 5 (5), C 6 H 5 CH 2 (6), C 6 F 5 (7), C 6 H 5 (8)) react with NEt 3 ´3 HF depending on the nature of R at 155±200 °C under replacement of the trimethylamine ligand to form