Completely stereoselective PC bond form
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Tin-Lok Au-Yeung; Ka-Yee Chan; Richard K Haynes; Ian D Williams; Lam Lung Yeung
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Article
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2001
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Elsevier Science
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French
⚖ 114 KB
Upon treatment with LDA or alkyllithium, enantiomers of P-chiral phosphinates, phosphinothioates, phosphinoamidates, thionophosphinates, thionophosphinothioates and thionophosphinoamidates undergo clean [1,3]-and [1,2]-rearrangements with complete stereoselectivity, with retention of configuration a