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Generation of Oligopeptides with Homochiral Sequences by Topochemical Reactions within Racemic Crystals of Phenylalanine-N-carboxyanhydride

✍ Scribed by José Geraldo Nery; Gérard Bolbach; Isabelle Weissbuch; Meir Lahav

Publisher: John Wiley and Sons
Year: 2003
Tongue: English
Weight: 159 KB
Volume: 42
Category: Article
ISSN: 0044-8249
DOI: 10.1002/anie.200351114

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## Abstract As part of our program on the search of possible prebiotic routes for the formation of oligopeptides of homochiral sequence (isotactic) from racemic precursors in aqueous environment, we report the polymerization of racemic crystals of phenylalanine __N__‐carboxyanhydrides, enantioselec