✦ LIBER ✦

Generation of [H3O]+.(H2O)n clusters by positive corona discharge in air

✍ Scribed by M. Pavlik; J. D. Skalny

Publisher: John Wiley and Sons
Year: 1997
Tongue: English
Weight: 185 KB
Volume: 11
Category: Article
ISSN: 0951-4198
DOI: 10.1002/(sici)1097-0231(19971030)11:16<1757::aid-rcm16>3.0.co;2-8

No coin nor oath required. For personal study only.

✦ Synopsis

A mass spectrometric study of ions extracted from DC positive corona discharges in ambient air has been carried out within the air pressure range of 2.5 kPa-20 kPa. The multicomponent character of the mass spectra was confirmed. The dominant series of ions observed in the mass spectra were of the type [H 3 O] + .(H 2 O) n especially in the low current regime. In the high current regime, or 'streamer' regime of the corona discharge, atomic nitrogen and oxygen ions were also discovered, but the intensities of these were relatively low in comparison with the intensities of peaks corresponding to the molecular ions. A new mechanism responsible for the disappearance of [O 2 ] + and its hydrated forms from the mass spectra is given. This is based on the set of stepwise processes originated by the three-body process:

📜 SIMILAR VOLUMES

ChemInform Abstract: Novel Pillared Laye

ChemInform Abstract: Novel Pillared Layer Structure of the Organically Templated Indium Phosphate (In8(HPO4)14(H2O)6)(H2O)5(H3O) (C3N2H5)3.

✍ A. M. CHIPPINDALE; S. J. BRECH; A. R. COWLEY; W. M. SIMPSON 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 30 KB

Ab initio molecular orbital study on str

Ab initio molecular orbital study on structures and energetics of CH3O−(H2O)n and CH3S−(H2O)n in gas phase

✍ Masao Masamura; Shigeru Ikuta 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 181 KB 👁 2 views

than the C-O bond length of CH O in the gas phase by 0.044 A at the 3 MP2raug-cc-pVDZ level of theory. The structure of the CH S y moiety in

ChemInform Abstract: Local Treatment of

ChemInform Abstract: Local Treatment of Electron Correlation in Molecular Clusters: Structures and Stabilities of (H2O)n, n = 2—4.

✍ M. SCHUETZ; G. RAUHUT; H.-J. WERNER 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 29 KB

ChemInform Abstract: Sulfur-Bridged Cuba

ChemInform Abstract: Sulfur-Bridged Cubane-Type Molybdenum-Gallium Clusters with Mo3GaSn+4 ( n = 5, 6) Cores. X-Ray Structures of (Mo3GaS4(H2O)12)(CH3C6H4SO3)5. times.14H2O and (Mo3GaS4(H2O)12)(CH3C6H4SO3)6×17H2O.

✍ T. SHIBAHARA; S. KOBAYASHI; N. TSUJI; G. SAKANE; M. FUKUHARA 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 36 KB

Ab Initio Molecular Dynamics Studies of

Ab Initio Molecular Dynamics Studies of Ionic Dissolution and Precipitation of Sodium Chloride and Silver Chloride in Water Clusters, NaCl(H2O)n and AgCl(H2O)n, n = 6, 10, and 14

✍ Chi-Kit Siu; Brigitte S. Fox-Beyer; Martin K. Beyer; Vladimir E. Bondybey 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 296 KB

An ab initio study of water clusters in

An ab initio study of water clusters in gas phase and bulk aqueous media: (H2O)n, n=1–12

✍ D. M. Upadhyay; M. K. Shukla; P. C. Mishra 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 263 KB 👁 2 views

Geometries of several clusters of water molecules including single minimum energy structures of n-mers (n = 1-5), several hexamers and two structures of each of heptamer to decamer derived from hexamer cage and hexamer prism were optimized. One structural form of each of 11-mer and 12-mer were also