✦ LIBER ✦

Generation of cold free radicals by the reaction of organic halides with metal atoms produced by laser vaporization

✍ Scribed by Ming Fang Cai; Terry A. Miller; V.E. Bondybey

Publisher: Elsevier Science
Year: 1989
Tongue: English
Weight: 419 KB
Volume: 158
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(89)87373-7

No coin nor oath required. For personal study only.

✦ Synopsis

Ba atoms are produced from a Ba rod by YAG laser vaporization in the throat of a seeded He supersonic jet expansion. As the expansion proceeds, the Ba atoms react with the seed gas, benzyl chloride. The reactron products, BaCl and benzyl radical, are observed substantially cooled downstream via laser-induced fluorescence.

📜 SIMILAR VOLUMES

The reactions of transition metal chelat

The reactions of transition metal chelates with organometallic compounds and their paramagnetic products. V—New possibilities in the generation of anion radicals by reactions of Grignard reagents and lithium alkyls in the presence of transition metal ions

✍ A. Staško; L. Malík; A. Tkáč; V. Adamčík; M. Hronec 📂 Article 📅 1977 🏛 John Wiley and Sons 🌐 English ⚖ 631 KB

## Abstract In the reactions of Grignard reagents and __n__‐butyllithium the presence of transition metals and complexing solvents facilitates the formation of anion radicals. High radical concentrations, observable for some days at laboratory temperature, and very well resolved e.s.r. spectra of t

E.s.r. study of the reaction of gases wi

E.s.r. study of the reaction of gases with the free radicals produced by u.v. radiation on the surfaces of acrylamide and some crystalline materials: 2. Results of H2, SO2 and CI2 admission to acrylamide, propionamide, methacrylamide and polyacrylamide

✍ Ulku Ramelow; Bahattin Baysal 📂 Article 📅 1987 🏛 Elsevier Science 🌐 English ⚖ 775 KB

E.s.r. study of the reactions of gases w

E.s.r. study of the reactions of gases with the free radicals produced by u.v. radiation on the surfaces of acrylamide and some crystalline materials: 1. Primary results of oxygen exposure to acrylamide, propionamide, methacrylamide and mixed crystals of these materials

✍ Ulku Ramelow; Bhattin Baysal 📂 Article 📅 1986 🏛 Elsevier Science 🌐 English ⚖ 597 KB