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Generation of bicyclo[4.1.0]heptatrienes. Carbene-carbene rearrangements in solution.

โœ Scribed by W.E. Billups; Larry E. Reed


Book ID
108383107
Publisher
Elsevier Science
Year
1977
Tongue
French
Weight
204 KB
Volume
18
Category
Article
ISSN
0040-4039

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Generation of bicyclo[4.1.0]heptatrienes
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Cyclopropylidene-bicyclo[1.1.0]butane in
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Pentacyclic (CH)a hydrocarbon 1 can be viewed not only as the most highly condensed valence isomer of cyclooctatetraene, but also as a formal (2+2) dimer of tetrahedrane. The effective cyclic conjugation of two bicyclo[l.l.O]butsne rings in 1 should form the basis for interesting spectral properties