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Generation of bicyclo[3.1.0]hexatriene. Reactive intermediate

โœ Scribed by Washburn, William N.


Book ID
126852565
Publisher
American Chemical Society
Year
1975
Tongue
English
Weight
274 KB
Volume
97
Category
Article
ISSN
0002-7863

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๐Ÿ“œ SIMILAR VOLUMES


Chemistry of bicyclo[3.1.0]hexatriene
โœ Washburn, William N.; Zahler, Robert ๐Ÿ“‚ Article ๐Ÿ“… 1976 ๐Ÿ› American Chemical Society ๐ŸŒ English โš– 416 KB
Generation and reactivity of sterically
โœ Richard F. Salinaro; Jerome A. Berson ๐Ÿ“‚ Article ๐Ÿ“… 1982 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 224 KB

Z-t-Butylbicyclo[3.1.O]hex-1-ene dimerizes primarily by a [o + IT] way, whereas 2,5-di-t-butylbicyclo[3.l.O]hex-1-ene undergoes an unusual hydrogen shift reaction to 1,3-di-t-butyl-2-methylcyclopentadiene. The presence of bulky substituents on or near the strained double bond of a bicyclo[3.l.O]hex-