## Abstract An efficient method of peptide thioester synthesis is described. The reaction is based on an __N__‐4,5‐dimethoxy‐2‐mercaptobenzyl (Dmmb) auxiliary‐assisted __N__‐__S__ acyl shift reaction after assembling a peptide chain by Fmoc‐solid phase peptide synthesis. The Dmmb‐assisted __N__‐__S
Generation of an S-Peptide via an N—S Acyl Shift Reaction in a TFA Solution.
✍ Scribed by Ken'ichiroh Nakamura; Megumi Sumida; Toru Kawakami; Thomas Vorherr; Saburo Aimoto
- Publisher
- John Wiley and Sons
- Year
- 2007
- Weight
- 17 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0931-7597
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✦ Synopsis
Abstract
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We report a study of the temperature dependence of the homogeneous width and frequency of the Sr + So O-O transitions of free-base pozphin as a guest in an n-octane matrix In the liquid helium temperature region, the measurements have been made by means of photochemicaf hole-burning, at hi&er temper