The reaction of BunLi with 2-substituted-l, 3-benzodithioles yields anions which react predictably with organic electrophiles to yield products in which the protected carbonyl group is readily unmasked. The anions constitute useful acyl carbanion equivalent 8.
β¦ LIBER β¦
Generation of 2-lithio-2-(methylthio)-1,3-benzodithioles, new carboxyl carbanion equivalents, and their application to the syntheses of unsymmetrical hexathioorthooxalates
β Scribed by Charles Allan Brown; Robert D. Miller; Charles M. Lindsay; Keith Smith
- Publisher
- Elsevier Science
- Year
- 1984
- Tongue
- French
- Weight
- 269 KB
- Volume
- 25
- Category
- Article
- ISSN
- 0040-4039
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